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Applicant:
Central University of Tamil Nadu 
Author:
Mr T Mohan Das  
Corresponding Authors:
M. K. Dhinakaran, K. Soundarajan 
DOI #:
10.1039/c4nj00038b 
Title:
Self-assembly of novel benzimidazole N-glycosylamines into nanofibers and nanospheres 
Journal:
New Journal of Chemistry 
Year:
2014 
Volume:
38 
Page:
2874-2883 
Keywords:
N-glycosylamines, benzimidazole, self-assembly, Morphological studies 
Abstract:
A novel class of benzimidazole based partially protected N-glycosylamine amphiphiles possessing different alkyl chains were synthesized in good yield. The identities of the synthesized N-glycosylamines were confirmed using 1H and 13C NMR and the molecular mass of representative samples was confirmed using MALDI-TOF mass analysis. All the benzimidazole based N-glycosylamines were found to exist in b-anomeric form, which was confirmed by 1H NMR analysis. Gelation studies showed that these compounds gelate both aromatic and aliphatic solvents, even at lower CGC (0.8%). The representative gel was studied using SEM, TEM and XRD techniques. The conversion of nanofibers in the gel state (CGC: 0.8%) into nanospheres was observed upon addition of Cu2+ ions. 
Entered by:
Mohan Das Thangamuthu on 2020-09-02 
 
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